A critical analysis of the degree of conversion of resin-based luting cements

J Appl Oral Sci. 2010 Sep-Oct;18(5):442-6. doi: 10.1590/s1678-77572010000500003.

Abstract

Objective: This study analyzed the degree of conversion (DC%) of four resin-based cements (All Ceram, Enforce, Rely X ARC and Variolink II) activated by two modes (chemical and dual), and evaluated the decrease of DC% in the dual mode promoted by the interposition of a 2.0-mm-thick IPS Empress 2 disc.

Material and methods: In the chemical activation, the resin-based cements were prepared by mixing equal amounts of base and catalyst pastes. In the dual activation, after mixing, the cements were light-activated at 650 mW/cm² for 40 s. In a third group, the cements were light-activated through a 2.0-mm-thick IPS Empress 2 disc. The DC% was evaluated in a FT-IR spectrometer equipped with an attenuated total reflectance crystal (ATR). The data were analyzed by two-way ANOVA and Tukey's HSD test.

Results: For all resin-based cements, the DC% was significantly higher with dual activation, followed by dual activation through IPS Empress 2, and chemical activation (p<0.05). Irrespective of the activation mode, Rely X presented the highest DC% (p<0.05). Chemically activated Variolink and All Ceram showed the worst results (p<0.05). The DC% decreased significantly when activation was performed through a 2.0-mm-thick IPS Empress 2 disc (p<0.05).

Conclusion: The results of the present study suggest that resin-based cements could present low DC% when the materials are dually activated through 2.0 mm of reinforced ceramic materials with translucency equal to or less than that of IPS-Empress 2.

MeSH terms

  • Bisphenol A-Glycidyl Methacrylate / chemistry
  • Bisphenol A-Glycidyl Methacrylate / radiation effects
  • Ceramics / chemistry
  • Curing Lights, Dental*
  • Hardness
  • Materials Testing
  • Methacrylates / chemistry
  • Methacrylates / radiation effects
  • Polyethylene Glycols / chemistry
  • Polyethylene Glycols / radiation effects
  • Polymerization / radiation effects*
  • Polymethacrylic Acids / chemistry
  • Polymethacrylic Acids / radiation effects
  • Resin Cements / chemistry*
  • Resin Cements / radiation effects
  • Spectroscopy, Fourier Transform Infrared
  • Surface Properties
  • Time Factors

Substances

  • Methacrylates
  • Polymethacrylic Acids
  • Resin Cements
  • triethylene glycol dimethacrylate
  • 2,2-bis-(4-(2-methacryloxyethoxy)phenyl)propane
  • Polyethylene Glycols
  • Bisphenol A-Glycidyl Methacrylate