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Dalton Trans. 2010 Sep 7;39(33):7640-4. doi: 10.1039/c0dt00618a. Epub 2010 Jul 26.

Clusters for alkyne-azide click reactions.

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  • 1Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9, A-1060, Wien, Austria.

Abstract

The clusters Ti(6)O(4)(OPr)(8)(OOC(CH(2))(2)C[triple bond]CH)(8) and [Zr(6)O(4)(OH)(4)(OOC(CH(2))(3)C[triple bond]CH)(12)](2) with acetylenic carboxylate ligands were prepared and structurally characterized in solution and in the crystalline state. Model reactions showed that they are suitable candidates for the formation of cluster-based inorganic-organic hybrid materials by alkyne-azide click reactions.

PMID:
20657938
[PubMed]
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