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Dalton Trans. 2010 Mar 7;39(9):2371-8. doi: 10.1039/b923211g. Epub 2010 Jan 19.

Self-assembly of silver(I) metallomacrocycles using unsupported 1,4-substituted-1,2,3-triazole "click" ligands.

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  • 1Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.


Readily synthesised mono- and di- 1,4-substituted-1,2,3-triazole "click" ligands are shown to self-assemble into discrete metallocyclic architectures with Ag(I) ions. The silver metallomacrocycles are stable in solution and the solid state and have been fully characterised by elemental analysis, HR-ESMS, IR, (1)H and (13)C NMR and in three cases the structures were confirmed by X-ray crystallography.

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