J Am Chem Soc. 2009 Nov 11;131(44):16042-4. doi: 10.1021/ja9075327.

Polymerization of enantiopure monomers using syndiospecific catalysts: a new approach to sequence control in polymer synthesis.

Kramer JW, Treitler DS, Dunn EW, Castro PM, Roisnel T, Thomas CM, Coates GW.

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Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York, 14853-1301, USA.

Abstract

The ring-opening polymerization of a mixture of enantiomerically pure but different monomers using an yttrium complex as initiator proceeds readily at room temperature to give the corresponding highly alternating polyester.

PMID:: 19835375; [PubMed - indexed for MEDLINE]

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Polymerization of enantiopure monomers using syndiospecific catalysts: a new approach to sequence control in polymer synthesis.
J Am Chem Soc. 2009 Nov 11 ;131(44):16042-4. doi: 10.1021/ja9075327.

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