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J Am Chem Soc. 2009 Sep 30;131(38):13613-5. doi: 10.1021/ja904189d.

Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry.

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  • 1Department of Chemistry and the Institute for Catalysis in Energy Processes, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA.

Abstract

A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using "click" chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were "clicked" onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.

PMID:
19736982
[PubMed]
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