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Chem Commun (Camb). 2009 Jul 7;(25):3720-2. doi: 10.1039/b823392f. Epub 2009 May 26.

A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration.

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  • 1Department of Chemistry and the Institute for Catalysis in Energy Processes, Northwestern University, Evanston, IL 60208-3113, USA.


A Zn-based, mixed-ligand (pillared paddlewheel), metal-organic framework (MOF) has been covalently and quantitatively decorated with free carboxylic acids to demonstrate the utility of covalent post-synthesis modification in the construction of otherwise inaccessible carboxy-functionalized MOFs.

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