Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions

Luca Pignataro; Benita Lynikaite; Raffaele Colombo; Stefano Carboni; Martin Krupicka; Umberto Piarulli; Cesare Gennari

doi:10.1039/b908167d

Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions

Chem Commun (Camb). 2009 Jun 28:(24):3539-41. doi: 10.1039/b908167d. Epub 2009 May 21.

Authors

Luca Pignataro¹, Benita Lynikaite, Raffaele Colombo, Stefano Carboni, Martin Krupicka, Umberto Piarulli, Cesare Gennari

Affiliation

¹ Dipartimento di Chimica Organica e Industriale, Centro Interdipartimentale C.I.S.I., Università degli Studi di Milano, Via G. Venezian 21, 20133 Milano, Italy.

PMID: 19521600
DOI: 10.1039/b908167d

Abstract

Heteroleptic complexes, formed selectively by using a 1 : 1 combination of a sigma-donor and a pi-acceptor ligand, are involved in Rh- and Pd-catalysed reactions.