Chem Pharm Bull (Tokyo). 2009 Jun;57(6):643-5.

Efficient synthesis of p-quinols using catalytic hypervalent iodine oxidation of 4-arylphenols with 4-iodophenoxyacetic acid and oxone.

Source

Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama, Sugitani, Toyama 930-0194, Japan. yakura@pha.u-toyama.ac.jp

Abstract

Efficient synthesis of p-quinols (2) using catalytic hypervalent iodine oxidation of 4-arylphenols (1) with 4-iodophenoxyacetic acid (3) and Oxone was developed. Reaction of 1 with a catalytic amount of 3 in the presence of Oxone as a co-oxidant in tetrahydrofuran or 1,4-dioxane-water gave the corresponding 2 in excellent yields.

PMID:: 19483353; [PubMed - indexed for MEDLINE]

Free full text

MeSH Terms, Substances

MeSH Terms

Substances

LinkOut - more resources

Full Text Sources

Other Literature Sources

Labome Researcher Resource - ExactAntigen/Labome

Supplemental Content

Save items

Related citations in PubMed

Catalytic hypervalent iodine oxidation of p-dialkoxybenzenes to p-quinones using 4-iodophenoxyacetic acid and Oxone. [Chem Pharm Bull (Tokyo). 2008]
Catalytic hypervalent iodine oxidation of p-dialkoxybenzenes to p-quinones using 4-iodophenoxyacetic acid and Oxone.
Yakura T, Yamauchi Y, Tian Y, Omoto M. Chem Pharm Bull (Tokyo). 2008 Nov; 56(11):1632-4.
Catalytic hypervalent iodine oxidation using 4-iodophenoxyacetic acid and oxone: oxidation of p-alkoxyphenols to p-benzoquinones. [Chem Pharm Bull (Tokyo). 2009]
Catalytic hypervalent iodine oxidation using 4-iodophenoxyacetic acid and oxone: oxidation of p-alkoxyphenols to p-benzoquinones.
Yakura T, Tian Y, Yamauchi Y, Omoto M, Konishi T. Chem Pharm Bull (Tokyo). 2009 Mar; 57(3):252-6.
An efficient catalytic oxidation of p-Alkoxypenols to p-quinones using tetrabutylammonium bromide and oxone. [Chem Pharm Bull (Tokyo). 2011]
An efficient catalytic oxidation of p-Alkoxypenols to p-quinones using tetrabutylammonium bromide and oxone.
Yakura T, Ozono A, Morimoto K. Chem Pharm Bull (Tokyo). 2011; 59(1):132-4.
Review [Development of rare metal-free synthetic method using new iodine reagents]. [Yakugaku Zasshi. 2009]
Review [Development of rare metal-free synthetic method using new iodine reagents].
Dohi T. Yakugaku Zasshi. 2009 Oct; 129(10):1187-99.
Review Stoichiometric and catalytic oxidations with hypervalent organo-lambda3-iodanes. [Chem Rec. 2007]
Review Stoichiometric and catalytic oxidations with hypervalent organo-lambda3-iodanes.
Ochiai M. Chem Rec. 2007; 7(1):12-23.

See reviews... See all...

Related information

Related Citations
Calculated set of PubMed citations closely related to the selected article(s) retrieved using a word weight algorithm. Related articles are displayed in ranked order from most to least relevant, with the “linked from” citation displayed first.
Compound (MeSH Keyword)
PubChem chemical compound records that are classified under the same Medical Subject Headings (MeSH) controlled vocabulary as the current articles.
Substance (MeSH Keyword)
PubChem chemical substance (submitted) records that are classified under the same Medical Subject Headings (MeSH) controlled vocabulary as the current articles.

Recent activity

Clear Turn Off Turn On

Efficient synthesis of p-quinols using catalytic hypervalent iodine oxidation of...
Efficient synthesis of p-quinols using catalytic hypervalent iodine oxidation of 4-arylphenols with 4-iodophenoxyacetic acid and oxone.
Chem Pharm Bull (Tokyo). 2009 Jun ;57(6):643-5.

PubMed
Suppression of N-myc downstream-regulated gene 2 is associated with induction of...
Suppression of N-myc downstream-regulated gene 2 is associated with induction of Myc in colorectal cancer and correlates closely with differentiation.
Biol Pharm Bull. 2009 Jun ;32(6):968-75.

PubMed
Variation in aggregation propensities among ALS-associated variants of SOD1: cor...
Variation in aggregation propensities among ALS-associated variants of SOD1: correlation to human disease.
Hum Mol Genet. 2009 Sep 1 ;18(17):3217-26. Epub 2009 May 30 .

PubMed
A randomized, controlled trial of bupropion sustained-release for preventing tob...
A randomized, controlled trial of bupropion sustained-release for preventing tobacco relapse in recovering alcoholics.
Nicotine Tob Res. 2009 Jul ;11(7):859-67. Epub 2009 May 29 .

PubMed
Platelet count response to H. pylori treatment in patients with immune thrombocy...
Platelet count response to H. pylori treatment in patients with immune thrombocytopenic purpura with and without H. pylori infection: a systematic review.
Haematologica. 2009 Jun ;94(6):850-6.

PubMed

Your browsing activity is empty.

Activity recording is turned off.

Turn recording back on

PubMed

Result Filters

Display Settings:

Send to: