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J Am Chem Soc. 2009 Jun 3;131(21):7206-7. doi: 10.1021/ja810050y.

Phthalimide-based polymers for high performance organic thin-film transistors.

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  • 1Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055, USA.

Abstract

The synthesis and characterization of two new thiophene copolymers with backbone phthalimide units is reported. Thin-film optical and wide-angle X-ray diffraction measurements indicate extended electronic conjugation and close intermolecular pi-stacking for both polymers. Ambient carrier mobility of thin-film transistors prepared from these polymers is as high as 0.28 cm(2)/(V s) with an on/off ratio greater than 10(5).

PMID:
19432417
[PubMed]
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