cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe III and Pd II coordination clusters

Graham N Newton; Geoffrey J T Cooper; Dominik Schuch; Takuya Shiga; Sumit Khanra; De-Liang Long; Hiroki Oshio; Leroy Cronin

doi:10.1039/b815200d

cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe III and Pd II coordination clusters

Dalton Trans. 2009 Mar 7:(9):1549-53. doi: 10.1039/b815200d. Epub 2009 Jan 26.

Authors

Graham N Newton¹, Geoffrey J T Cooper, Dominik Schuch, Takuya Shiga, Sumit Khanra, De-Liang Long, Hiroki Oshio, Leroy Cronin

Affiliation

¹ WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow, UK.

PMID: 19421597
DOI: 10.1039/b815200d

Abstract

A dodecanuclear Fe(III) complex, consisting of two {Fe(6)} units coupled across a single hydroxy-bridge and a cage-like Pd(II) trimer were synthesised using the highly branched, pentadecadentate chelating ligand cis,cis-1,3,5-cyclohexanetriamine-N,N,N',N',N'',N''-hexaacetic acid (H(6)hact).

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Crystallography, X-Ray
Ferric Compounds / chemistry*
Ligands
Organometallic Compounds / chemical synthesis*
Organometallic Compounds / chemistry
Palladium / chemistry*

Substances

Ferric Compounds
Ligands
Organometallic Compounds
Palladium