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Chem Commun (Camb). 2009 Feb 7;(5):550-2. doi: 10.1039/b817371k. Epub 2008 Dec 4.

Catalytic electrochemistry of a [NiFeSe]-hydrogenase on TiO2 and demonstration of its suitability for visible-light driven H2 production.

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  • 1Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK OX1 3QR.


A [NiFeSe]-hydrogenase able to produce H(2) in the presence of O(2) forms the basis of a hybrid enzyme-TiO(2) nanoparticle system with a co-attached synthetic Ru photosensitiser for visible-light driven H(2) production at room temperature from neutral water under non-strictly anaerobic conditions on the bench.

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