Evaluation of lithium ion insertion reactivity via electrochromic diffraction-based imaging

Lilia V Kondrachova; R Alan May; Craig W Cone; David A Vanden Bout; Keith J Stevenson

doi:10.1021/la803245a

Evaluation of lithium ion insertion reactivity via electrochromic diffraction-based imaging

Langmuir. 2009 Feb 17;25(4):2508-18. doi: 10.1021/la803245a.

Authors

Lilia V Kondrachova¹, R Alan May, Craig W Cone, David A Vanden Bout, Keith J Stevenson

Affiliation

¹ Department of Chemistry and Biochemistry, Center for Nano- and Molecular Science and Technology, Texas Materials Institute, University of Texas at Austin, Austin, Texas 78712, USA.

PMID: 19154121
DOI: 10.1021/la803245a

Abstract

A microscope-CCD setup has been developed as an analytical tool for the detection of diffraction from one-dimensional redox-active transition-metal oxide gratings prepared with a combination of microtransfer molding (microTM) and cathodic electrodeposition. The diffraction efficiencies (DE) of tungsten trioxide, WO3, and binary molybdenum-tungsten trioxide, Mo0.6W0.4O3, gratings were measured during Li+ insertion/deinsertion experiments performed with both cyclic voltammetry and chronoamperometry in 1 M LiClO4/propylene carbonate. The DE was evaluated in terms of the optical constants of the grating materials determined by spectroscopic ellipsometry (SE) measurements of Li+ insertion/deinsertion into unpatterned thin films. The effect of grating thickness and the amount of inserted charge on DE has been analyzed. The diffraction method is used to quantitatively estimate lithium ion diffusion coefficients of electrochemically active metal oxide gratings.