Format

Send to:

Choose Destination
See comment in PubMed Commons below
Inorg Chem. 2009 Jan 19;48(2):426-8. doi: 10.1021/ic801677y.

Pillared porphyrin homologous series: intergrowth in metal-organic frameworks.

Author information

  • 1Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska 68588-0304, USA.

Abstract

We report three new porphyrin-based, pillared paddle-wheel homologous series: porphyrin paddle-wheel frameworks PPF-3, -4, and -5. These compounds are assembled from free base or palladium tetrakis(4-carboxyphenyl)porphine, M(NO(3))(2) (M = Co and Zn), and 4,4'-bipyridine via solvothermal reactions. The resulting solids exhibit 3D metal-organic frameworks, where 2D layers are pillared by bipyridine with three different packing arrangements.

PMID:
19090682
[PubMed]
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for American Chemical Society
    Loading ...
    Write to the Help Desk