Display Settings:

Format

Send to:

Choose Destination
See comment in PubMed Commons below
Dalton Trans. 2008 Nov 21;(43):6023-9. doi: 10.1039/b806544f. Epub 2008 Sep 22.

Synthesis of palladacycles employing iminoisoindolines as monoanionic bidentate ligands.

Author information

  • 1University of Saskatchewan, Department of Chemistry, 110 Science Place, S7N 5C9, Saskatoon, Saskatchewan, Canada.

Abstract

A series of air- and moisture-stable iminoisoindoline-based palladacycles have been prepared in two operationally simple steps from commercially available reagents. para-Substituted N,N'-diphenyliminoisoindoline ligands are easily synthesized from phthalaldehyde and para-substituted anilines and further reaction of the iminoisoindoline ligands with Pd(OAc)(2) in dichloromethane at room temperature results in formation of six-membered [C,N] dinuclear cyclopalladated complexes with the general formula [(iminoisoindoline)Pd(micro-OAc)](2). The resulting palladacyclic complexes were tested as precatalysts in Heck and Suzuki coupling reactions.

PMID:
19082059
[PubMed]
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for Royal Society of Chemistry
    Loading ...
    Write to the Help Desk