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Chem Commun (Camb). 2009 Jan 7;(1):74-6. doi: 10.1039/b815540b. Epub 2008 Nov 13.

Organic functionalization of mesopore walls in hierarchically porous zeolites.

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  • 1Department of Chemistry, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Korea.

Abstract

Mesopore walls of hierarchically meso-/microporous zeolites (MFI, BEA and LTA) are covered with silanol groups, so that the zeolites can be functionalized with various organic groups via silylation; the organic-functionalized hierarchical zeolites exhibit hydrothermal stability and reusability in catalytic applications, as compared with organic-functionalized mesoporous silica.

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