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Chem Commun (Camb). 2008 Nov 21;(43):5619-21. doi: 10.1039/b811746b. Epub 2008 Sep 29.

A two-step spin crossover mononuclear iron(II) complex with a [HS-LS-LS] intermediate phase.

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  • 1Leiden Institute of Chemistry, Leiden University, RA2300, Leiden, The Netherlands.

Abstract

The two-step spin crossover of a new mononuclear iron(ii) complex is studied by magnetic, crystallographic and calorimetric methods revealing two successive first-order phase transitions and an ordered intermediate phase built by the repetition of the unprecedented [HS-LS-LS] motif.

PMID:
18997971
[PubMed - indexed for MEDLINE]
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