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Chem Commun (Camb). 2008 Oct 28;(40):4894-6. doi: 10.1039/b811865e. Epub 2008 Sep 22.

Isomorphous CoII and MnII materials of tetrazolate-5-carboxylate with an unprecedented self-penetrating net and distinct magnetic behaviours.

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  • 1Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai, 200062, China.


Two isomorphous Co(II) and Mn(II) three-dimensional coordination polymers with tetrazolate-5-carboxylate as magnetic mediator exhibit an unprecedented 3,4-connected self-penetrating net topology; a combination of canted antiferromagnetism and metamagnetism was observed in the Co(II) compound, whereas the Mn(II) compound shows typical antiferromagnetic behaviors.

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