Format

Send to:

Choose Destination
See comment in PubMed Commons below
Chem Soc Rev. 2008 Sep;37(9):1931-51. doi: 10.1039/b708845k. Epub 2008 Jul 15.

A briefing on aurophilicity.

Author information

  • 1Department Chemie, Technische Universit√§t M√ľnchen, 85747, Garching, Germany.

Erratum in

  • Chem Soc Rev. 2012 Dec 21;41(24):8212.

Abstract

There is now compelling experimental evidence for the existence of specific intra- and intermolecular bonding between seemingly closed-shell gold(I) centers (5d10) which manifests itself in all areas of gold chemistry. This "aurophilic interaction", which had not been predicted by conventional valence theory, was found to be associated with binding energies in some cases exceeding even those of strong hydrogen bonds and therefore to be highly significant in co-determining molecular structure and dynamics. In high-level theoretical treatments the attraction is rationalized as a "super van der Waals bonding" based on particularly strong relativistic, dispersion and correlation effects (critical review, 265 references).

PMID:
18762840
[PubMed]
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for Royal Society of Chemistry
    Loading ...
    Write to the Help Desk