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Org Lett. 2008 Oct 2;10(19):4187-90. doi: 10.1021/ol801590j. Epub 2008 Aug 28.

Nonracemic diarylmethanols from CuH-catalyzed hydrosilylation of diaryl ketones.

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  • 1Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA.

Abstract

An efficient method for the synthesis of nonracemic diarylmethanols has been developed. The use of ( R)-(-)-(DTBM-SEGPHOS)CuH effects highly enantioselective 1,2-hydrosilylation of prochiral diaryl ketones.

PMID:
18754623
[PubMed - indexed for MEDLINE]
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