A system for measurement of the spectral radiance of materials shocked to high pressures ( approximately 100 GPa) by impact using a light gas gun is described. Thermal radiation from the sample is sampled at six wavelength bands in the visible spectrum, and each signal is separately detected by solid-state photodiodes, and recorded with a time resolution of approximately 10 ns. Interpretation of the records in terms of temperature of transparent sample materials is discussed. Results of a series of exploratory experiments with metals are also given. Shock temperatures in the range 4000-8000 K have been reliably measured. Spectral radiance and temperatures have been determined with uncertainties of 2%.