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J Am Chem Soc. 2008 Jun 25;130(25):7778-9. doi: 10.1021/ja800439p. Epub 2008 May 30.

Temperature controlled reversible change of the coordination modes of the highly symmetrical multitopic ligand to construct coordination assemblies: experimental and theoretical studies.

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  • 1State Key Laboratory of Coordination Chemistry and Institute of Theoretical and Computational Chemistry, Nanjing University, Nanjing 210093, PR China.

Abstract

By fine-tuning the reaction temperature to 5, 15, 30, and 50 degrees C, respectively, four different complexes, [Cd(HC4O4)2(H2O)4] (1), [Cd4(C4O4)4(H2O)16].(H2O)2 (2), [Cd(C4O4)(H2O)2] (3), and [Cd(C4O4)(H2O)2] (4), were formed successfully from the identical initial reaction mixture. Moreover, an unprecedented reversible interconversion among the four complexes at the corresponding reaction temperatures mediated by the mother liquor was observed.

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