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Chem Commun (Camb). 2008 Mar 21;(11):1293-5. doi: 10.1039/b718678a. Epub 2008 Feb 15.

Highly active and stereoselective zirconium and hafnium alkoxide initiators for solvent-free ring-opening polymerization of rac-lactide.

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  • 1Department of Chemistry, University of Bath, Claverton Down, Bath, UK.

Erratum in

  • Chem Commun (Camb). 2008 Dec 28;(48):6611.

Abstract

Under solvent-free conditions (at 130 degrees C), zirconium and hafnium amine tris(phenolate) alkoxides are extremely active, well-controlled, single-site initiators for the ring-opening polymerization of rac-lactide, yielding highly heterotactic polylactide.

PMID:
18389111
[PubMed - indexed for MEDLINE]
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