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Chirality. 2008 Sep;20(9):973-7. doi: 10.1002/chir.20539.

Dendritic crystal growth, differential circular scattering, and the origin of biomolecular homochirality.

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  • 1Department of Chemistry, University of Washington, Seattle, Washington 98195-1700, USA. kahr@chem.washington.edu

Abstract

Phthalic acid rapidly crystallizing in thin aqueous films is deposited radially and rhythmically as dendritic banded spherulites that have heterochiral meso-textures in hemi-circles. The chiral fields differentially scatter left and right circularly polarized light. A scenario for chiral amplification and the origin of biomolecular homochirality is thus proposed that combines the influences of crystals and light.

(c) 2008 Wiley-Liss, Inc.

PMID:
18311779
[PubMed - indexed for MEDLINE]
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