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J Am Chem Soc. 2008 Feb 6;130(5):1574-5. doi: 10.1021/ja710384t. Epub 2008 Jan 11.

Formation and stability of a vinyl carbanion at the active site of orotidine 5'-monophosphate decarboxylase: pKa of the C-6 proton of enzyme-bound UMP.

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  • 1Department of Chemistry, University at Buffalo, Buffalo, New York 14260, USA.
PMID:
18186641
[PubMed - indexed for MEDLINE]
PMCID:
PMC2652670
Free PMC Article

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