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Chem Commun (Camb). 2007 Sep 7;(33):3467-9. Epub 2007 Jul 31.

The dramatic acceleration effect of imidazolium ionic liquids on electron transfer reactions.

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  • 1Department of Chemistry, Institute of Basic Science, Sungkyunkwan University, Suwon 440-746, Korea.

Abstract

Imidazolium ionic liquids (ILs) exhibited a dramatic acceleration effect on the electron transfer from metal complexes such as (C(5)Me(5))(2)Fe(II) and (C(5)Me(5))(2)Co(II) to the oxygen molecule; this acceleration effect can be ascribed to the stabilization of the oxygen radical anions by coordinating with the acidic C2-H of imidazolium ILs.

PMID:
17700884
[PubMed]
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