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J Am Chem Soc. 2007 Aug 1;129(30):9284-5. Epub 2007 Jul 11.

Dinitrogen activation at ambient temperatures: new modes of H(2) and PhSiH(3) additions for an "End-On-Bridged" [Ta(IV)](2)(mu-eta(1):eta(1)-N(2)) complex and for the bis(mu-nitrido) [Ta(V)(mu-N)](2) product derived from facile NN bond cleavage.

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  • 1Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA.
PMID:
17625853
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