A novel light-cured glass-ionomer system for improved dental restoratives

J Mater Sci Mater Med. 2007 Oct;18(10):1907-16. doi: 10.1007/s10856-007-3100-z. Epub 2007 Jun 2.

Abstract

A novel light-cured glass-ionomer cement (LCGIC) system based on the 4-arm star-shape poly(acrylic acid) (AA) tethered with glycidyl methacrylate has been developed. The 4-arm poly(AA) polymer was synthesized using atom-transfer radical polymerization. The purified polymer was used to formulate with water and Fuji II LC filler to form LCGICs. Compressive strength (CS) was used as a screening tool for evaluation. The effects of grafting ratio, polymer/water (P/W) ratio, filler powder/polymer liquid (P/L) ratio and aging on strengths were investigated. All the specimens were conditioned in distilled water at 37 degrees C for 24 h prior to testing. The results show that the 4-arm poly(AA) polymer exhibited a lower viscosity as compared to its linear counterpart that was synthesized via conventional free-radical polymerization. This novel LCGIC system was 13% in CS, 86% in diametral tensile strength (DTS) and 123% in flexural strength higher but 93.6% in shrinkage lower than Fuji II LC. Increasing P/W ratio significantly increased both CS and DTS. Upon increasing grafting ratio, the CS was increased from 35% to 50% but not from 50% to 70%. Likewise, when P/L ratio was increased, the CS was increased from 2.2 to 2.7 but not from 2.7 to 3.0. During aging, the ultimate CS (MPa) was significantly increased from 209.2 at 1 h to 329.7 at 1 week. It appears that this novel LCGIC system will be a better dental restorative because it demonstrated improved mechanical strengths as well as little shrinkage and may eliminate cytotoxicity in current LCGICs caused by leached HEMA.

Publication types

  • Evaluation Study
  • Research Support, N.I.H., Extramural

MeSH terms

  • Compressive Strength / drug effects
  • Dental Restoration, Permanent*
  • Glass Ionomer Cements / chemical synthesis*
  • Glass Ionomer Cements / chemistry*
  • Light*
  • Materials Testing
  • Models, Biological
  • Polymers
  • Powders / pharmacology
  • Resins, Synthetic / chemistry
  • Water / chemistry

Substances

  • Fuji II LC cement
  • Glass Ionomer Cements
  • Polymers
  • Powders
  • Resins, Synthetic
  • Water