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Org Lett. 2007 Jun 21;9(13):2441-4. Epub 2007 Jun 2.

Development of a catalytic aromatic decarboxylation reaction.

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  • 1Department of Chemistry, Roy and Diana Vagelos Laboratories, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA.


A palladium-catalyzed aromatic decarboxylation reaction has been developed. With electron-rich aromatic acids, the reaction proceeds efficiently under fairly mild conditions in good yields. The method was useful with complex functionalized substrates containing hindered carboxylic acids.

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