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J Org Chem. 2007 May 11;72(10):3875-9. Epub 2007 Apr 10.

Enantio- and regioselective heck-type reaction of arylboronic acids with 2,3-dihydrofuran.

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  • 1Department of Organic Chemistry, The Hebrew University of Jerusalem, Jerusalem, 91904 Israel.


Reported herein is a protocol for the enantioselective Pd(II)-catalyzed Heck-type reaction between arylboronic acids and 2,3-dihydrofuran. The highest chemical and optical yields were obtained when a Pd(OAc)2/(R)-MeO(biphenylphosphine) or a Pd(OAc)2/(R)-(2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) catalyst and a Cu(OAc)2 reoxidant were employed.

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