Format

Send to:

Choose Destination
See comment in PubMed Commons below
Org Lett. 2007 Apr 26;9(9):1647-9. Epub 2007 Mar 31.

Palladium-catalyzed synthesis of highly substituted endocyclic enol lactones via a three-component coupling reaction in an ionic liquid.

Author information

  • 1Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada K1N 6N5.

Abstract

[reaction: see text] A new, efficient ionic liquid based synthetic procedure was developed for the preparation of highly substituted endocyclic enol lactones via the carbonylation coupling reactions of alkynes and 1,3-diketones in ionic liquid. The reactions proceeded in excellent regioselectivity and in reasonably good yields. The catalyst system can be recycled five times with only modest loss of its catalytic activity.

PMID:
17397171
[PubMed - indexed for MEDLINE]
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for American Chemical Society
    Loading ...
    Write to the Help Desk