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Inorg Chem. 2007 Feb 5;46(3):604-6.

Zeolite-like copper iodide framework with new 6(6) topology.

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  • 1State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, People's Republic of China.


We have described an unprecedented three-dimensional zeolite-like copper iodide constructed from Cu4I4(DABCO)4 (DABCO = 1,4-diazabicyclo[2.2.2]octane) supertetrahedron units. This compound forms a four-connected network with new 6(6) topology. Its structure reveals one-dimensional channels along the [001] direction, and the framework displays interesting self-penetration. The title compound shows photoluminescence at room temperature in the solid state.

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