An unusually high thermal stability within a novel lanthanide 1,3,5-cyclohexanetricarboxylate framework: synthesis, structure, and thermal data

Daniel T de Lill; Christopher L Cahill

doi:10.1039/b610012k

An unusually high thermal stability within a novel lanthanide 1,3,5-cyclohexanetricarboxylate framework: synthesis, structure, and thermal data

Chem Commun (Camb). 2006 Dec 21:(47):4946-8. doi: 10.1039/b610012k. Epub 2006 Oct 6.

Authors

Daniel T de Lill¹, Christopher L Cahill

Affiliation

¹ Department of Chemistry, The George Washington University, Washington, DC, 20052, USA.

PMID: 17136256
DOI: 10.1039/b610012k

Abstract

A novel three-dimensional lanthanide-organic framework has been synthesized; this material has an exceptionally high thermal stability (600 degrees C) and an unusually low coordination number for a lanthanide ion (CN = 6).

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Carboxylic Acids / chemistry*
Crystallography, X-Ray
Cyclohexanes / chemistry*
Lanthanoid Series Elements / chemistry*
Models, Molecular
Organometallic Compounds / chemical synthesis*
Organometallic Compounds / chemistry*
Temperature*

Substances

1,3,5-cyclohexanetricarboxylate
Carboxylic Acids
Cyclohexanes
Lanthanoid Series Elements
Organometallic Compounds