Abstract
Two novel coordination polymers, Cu3(4-pyt)3 (1) and Co(4-pyt)2 (2) (4-pyt = pyridine-4-thiolate), have been synthesized by in situ generation of a 4-pyt ligand from a 4,4'-dithiodipyridine precursor through reductive cleavage of the disulfide bond under solvothermal conditions. 1 and 2 exhibit a three-dimensional (3,4)-connected network and a two-dimensional square-grid-type structure, respectively.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Chemistry, Inorganic / methods*
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Disulfides* / chemistry
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Hot Temperature
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Ligands
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Models, Chemical
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Models, Molecular
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Molecular Conformation
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Polymers / chemistry*
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Spectrophotometry, Ultraviolet
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Sulfides / chemistry
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Temperature
Substances
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Disulfides
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Ligands
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Polymers
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Sulfides