Mechanism of NO transfer from NO-donors (SNAP and G-MNBS) to ferrous tetraphenylporphyrin in CH3OH

Xiao-Qing Zhu; Jian-Yu Zhang; Lian-Rui Mei; Jin-Pei Cheng

doi:10.1021/ol061021m

Mechanism of NO transfer from NO-donors (SNAP and G-MNBS) to ferrous tetraphenylporphyrin in CH3OH

Org Lett. 2006 Jul 6;8(14):3065-7. doi: 10.1021/ol061021m.

Authors

Xiao-Qing Zhu¹, Jian-Yu Zhang, Lian-Rui Mei, Jin-Pei Cheng

Affiliation

¹ Department of Chemistry, the State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, China. xqzhu@nankai.edu.cn

PMID: 16805553
DOI: 10.1021/ol061021m

Abstract

[reaction: see text] The mechanism of NO transfer from NO-donors (SNAP and G-MNBS) to ferrous tetraphenylporphyrin (TPPFe(II)) in CH(3)OH is discovered for the first time by using a laser flash technique. The results show that the NO transfer is completed by NO(+) transfer followed by electron transfer rather than direct NO transfer in one step.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Benzenesulfonates / chemistry*
Methanol / chemistry
Molecular Structure
Nitric Oxide / chemistry*
Nitric Oxide Donors / chemistry*
Penicillamine / analogs & derivatives*
Penicillamine / chemistry
Porphyrins / chemistry*

Substances

Benzenesulfonates
Nitric Oxide Donors
Porphyrins
S-nitro-N-acetylpenicillamine
tetraphenylporphyrin
Nitric Oxide
methyl-4-nitrobenzenesulfonate
Penicillamine
Methanol