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J Am Chem Soc. 2006 Jul 5;128(26):8410-1.

C-C bond-forming reductive elimination from a zirconium(IV) redox-active ligand complex.

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  • 1Department of Chemistry, University of California-Irvine, Irvine, CA 92697, USA.

Abstract

Carbon-carbon bond-forming reductive elimination of biphenyl is observed upon two-electron oxidation of the [ZrIVPh2(ap)2]2- dianion. Crossover experiments confirm that the C-C bond-forming step occurs at a single zirconium metal center. The reactivity is enabled by the participation of a redox-active amidophenolate ligand set.

PMID:
16802801
[PubMed]
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