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Org Lett. 2006 Jun 8;8(12):2523-6.

A simple catalytic method for the regioselective halogenation of arenes.

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  • 1University of Michigan, Department of Chemistry, 930 North University Avenue, Ann Arbor, MI 48109-1055, USA.


This paper describes a mild palladium-catalyzed method for the regioselective chlorination, bromination, and iodination of arene C-H bonds using N-halosuccinimides as oxidants. These transformations have been applied to a wide array of substrates and can provide products that are complementary to those obtained via conventional electrophilic aromatic substitution reactions. [reaction: see text]

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