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J Am Chem Soc. 2006 Apr 19;128(15):4926-7.

A photo-hydrogen-evolving molecular device driving visible-light-induced EDTA-reduction of water into molecular hydrogen.

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  • 1Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan.

Abstract

A photo-hydrogen-evolving molecular device made up of a tris(2,2'-bipyridine)ruthenium(II) derivative and a dichloro(2,2'-bipyridine)platinum(II) derivative has been found to serve as the first effective model of a "molecular device" which evolves molecular hydrogen from water in the presence of a sacrificial electron donor (EDTA), under the visible-light illumination.

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