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Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, USA.
A way to circumvent the high pressures needed to metallize hydrogen is to "precompress" it in hydrogen-rich molecules, a strategy probed theoretically for silane. We show that phases with tetrahedral SiH4 molecules should undergo phase transitions with sixfold- and eightfold-coordinate Si appearing above 25 GPa. The most stable structure found can be metallized at under a megabar and at a compression close to the prediction of Goldhammer-Herzfeld criterion. According to a BCS-like estimate, metallic silane should be a high-temperature superconductor.
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