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Inorg Chem. 2005 Dec 26;44(26):9628-30.

Oxygen binding of water-soluble cobalt porphyrins in aqueous solution.

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  • 1Department of Chemistry, Stanford University, California 94305-5080, USA. jpc@stanford.edu


Water-soluble cobalt porphyrin 1Co and imidazole ligand 2 were synthesized. 1Co binds dioxygen in the presence of imidazole ligand 2 in aqueous solution. The formation of the oxygen adduct 2-1Co(O(2)) was studied using UV-vis and EPR spectroscopy. The impact of pH on the kinetic stability of the oxygen adduct was examined.

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