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Org Lett. 2005 Sep 15;7(19):4293-6.

Chiral binaphthyl-derived amine-thiourea organocatalyst-promoted asymmetric Morita-Baylis-Hillman reaction.

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  • 1Department of Chemistry, University of New Mexico, Albuquerque, New Mexico 87131-0001, USA.

Abstract

[reaction: see text] A new bifunctional binaphthyl-derived amine thiourea organocatalyst has been developed to promote enantioselective Morita-Baylis-Hillman reaction of cyclohexenone with a wide range of aldehydes. The process, catalyzed by the amine thiourea, affords synthetically valuable chiral allylic alcohol building blocks in high yields and high enantioselectivities.

PMID:
16146410
[PubMed - indexed for MEDLINE]
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