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Org Lett. 2005 Jul 7;7(14):3017-20.

Salvinicins A and B, new neoclerodane diterpenes from Salvia divinorum.

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  • 1Division of Medicinal & Natural Products Chemistry, The University of Iowa, Iowa City, 52242, USA.


[reaction: see text] Two new neoclerodane diterpenes, salvinicins A (4) and B (5), were isolated from the dried leaves of Salvia divinorum. The structures of these compounds were elucidated by spectroscopic techniques, including (1)H and (13)C NMR, NOESY, HMQC, and HMBC. The absolute stereochemistry of these compounds was assigned on the basis of single-crystal X-ray crystallographic analysis of salvinicin A (4) and a 3,4-dichlorobenzoate derivative of salvinorin B.

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