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J Am Chem Soc. 2005 May 25;127(20):7328-9.

Dithiocarbamate assembly on gold.

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  • 1Department of Chemistry, Purdue University, West Lafayette, Indiana 47907-2084, USA.

Abstract

Au surfaces are functionalized by stable dithiocarbamate ligands when exposed to carbon disulfide and secondary amines. The adsorbed dithiocarbamates are robust under a wide pH range and can resist displacement by other chemisorptive surfactants, providing an attractive method for conjugating sensitive molecules onto metal surfaces.

PMID:
15898778
[PubMed - indexed for MEDLINE]
PMCID:
PMC1766936
Free PMC Article
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