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Chem Commun (Camb). 2005 Mar 7;(9):1191-3. Epub 2005 Jan 18.

Polyoxoanions functionalized by diorganotin groups: the tetrameric, chiral tungstoarsenate(III), [{Sn(CH3)2(H2O)}2{Sn(CH3)2}As3(alpha-AsW9O33)4]21-.

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  • 1International University Bremen, School of Engineering and Science, PO Box 750 561, 28725 Bremen, Germany.

Abstract

The tetrameric, hybrid organic-inorganic tungstoarsenate(III) [{Sn(CH3)2(H2O)}2{Sn(CH3)2}As3(alpha-AsW9O33)4]21- is composed of four (B-alpha-AsW9O33) fragments that are linked by three dimethyltin groups and three As(III) atoms resulting in an unprecedented, chiral polyoxoanion assembly with C1 symmetry.

PMID:
15726188
[PubMed]
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