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Chem Commun (Camb). 2005 Feb 28;(8):1085-6. Epub 2005 Jan 12.

Polymer-supported nitroxyl radical catalyst for selective aerobic oxidation of primary alcohols to aldehydes.

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  • 1Johnson Matthey Catalysts, PO Box 1, Belasis Avenue, Billingham, Cleveland, UK TS23 1LB.

Abstract

PS-TEMPO, a polymer-supported 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO), was successfully applied as a recyclable, active and selective catalyst for the oxidation of primary aliphatic and benzylic alcohols to aldehydes by molecular oxygen in the presence of Co(NO3)2 and Mn(NO3)2 as co-catalysts.

PMID:
15719124
[PubMed]
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