Org Lett. 2005 Jan 20;7(2):251-3.

A two-step reaction sequence for the syntheses of tetrahydronaphthalenes.

Source

Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35032 Marburg, Germany. hilt@chemie.uni-marburg.de

Abstract

[Reaction: see text] A cobalt(I)-catalyzed Diels-Alder reaction of a boron-functionalized enyne is the key step in a two-step reaction cascade interconnecting four simple starting materials to obtain polycyclic multifunctionalized products in good yields and with a very high degree of diastereoselectivity.

PMID:: 15646970; [PubMed - indexed for MEDLINE]

Publication Types, MeSH Terms, Substances

Publication Types

Research Support, Non-U.S. Gov't

MeSH Terms

Substances

LinkOut - more resources

Full Text Sources

Other Literature Sources

Molecular Biology Databases

COBALT - HSDB

Supplemental Content

Save items

Related citations in PubMed

Asymmetric cobalt-catalyzed Diels-Alder reactions of a boron-functionalized 1,3-diene with alkynes and allylboration with aldehydes. [Org Lett. 2006]
Asymmetric cobalt-catalyzed Diels-Alder reactions of a boron-functionalized 1,3-diene with alkynes and allylboration with aldehydes.
Hilt G, Hess W, Harms K. Org Lett. 2006 Jul 20; 8(15):3287-90.
Chemo-, regio-, and stereoselective cobalt-mediated [2+2+2] cycloaddition of alkynyl boronates to alkenes: 1,3- and 1,4-diboryl-1,3-cyclohexadienes. [Angew Chem Int Ed Engl. 2005]
Chemo-, regio-, and stereoselective cobalt-mediated [2+2+2] cycloaddition of alkynyl boronates to alkenes: 1,3- and 1,4-diboryl-1,3-cyclohexadienes.
Gandon V, Leboeuf D, Amslinger S, Vollhardt KP, Malacria M, Aubert C. Angew Chem Int Ed Engl. 2005 Nov 4; 44(43):7114-8.
Remarkable access to fluoroalkylated trisubstituted alkenes via highly stereoselective cobalt-catalyzed hydrosilylation reaction of fluoroalkylated alkynes. [Org Biomol Chem. 2009]
Remarkable access to fluoroalkylated trisubstituted alkenes via highly stereoselective cobalt-catalyzed hydrosilylation reaction of fluoroalkylated alkynes.
Konno T, Taku K, Yamada S, Moriyasu K, Ishihara T. Org Biomol Chem. 2009 Mar 21; 7(6):1167-70. Epub 2009 Jan 29.
Review Catalytic synthesis of oligoene and enyne derivatives through carbometalation of internal alkynes. [Chem Rec. 2008]
Review Catalytic synthesis of oligoene and enyne derivatives through carbometalation of internal alkynes.
Satoh T, Tsurugi H, Miura M. Chem Rec. 2008; 8(5):326-36.
Review Elementary reactions of boron atoms with hydrocarbons-toward the formation of organo-boron compounds. [Chem Rev. 2010]
Review Elementary reactions of boron atoms with hydrocarbons-toward the formation of organo-boron compounds.
Balucani N, Zhang F, Kaiser RI. Chem Rev. 2010 Sep 8; 110(9):5107-27.

See reviews... See all...

Related information

Related Citations
Calculated set of PubMed citations closely related to the selected article(s) retrieved using a word weight algorithm. Related articles are displayed in ranked order from most to least relevant, with the “linked from” citation displayed first.
Compound (MeSH Keyword)
PubChem chemical compound records that are classified under the same Medical Subject Headings (MeSH) controlled vocabulary as the current articles.
Substance (MeSH Keyword)
PubChem chemical substance (submitted) records that are classified under the same Medical Subject Headings (MeSH) controlled vocabulary as the current articles.

Recent activity

Clear Turn Off Turn On

A two-step reaction sequence for the syntheses of tetrahydronaphthalenes.
A two-step reaction sequence for the syntheses of tetrahydronaphthalenes.
Org Lett. 2005 Jan 20 ;7(2):251-3.

PubMed
Understanding dentists' restorative treatment decisions.
Understanding dentists' restorative treatment decisions.
J Public Health Dent. 1992 Winter ;52(2):102-10.

PubMed
In vivo activity of the potent oxytocin antagonist on uterine activity in the ra...
In vivo activity of the potent oxytocin antagonist on uterine activity in the rat.
In Vivo. 2004 Nov-Dec ;18(6):763-6.

PubMed
A prospective treatment study of premenstrual symptoms using a triphasic oral co...
A prospective treatment study of premenstrual symptoms using a triphasic oral contraceptive.
J Psychosom Res. 1992 Apr ;36(3):257-66.

PubMed
Burnout in residency: a statewide study.
Burnout in residency: a statewide study.
South Med J. 2004 Dec ;97(12):1171-3.

PubMed

Your browsing activity is empty.

Activity recording is turned off.

Turn recording back on

PubMed

Result Filters

Display Settings:

Send to: