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Org Lett. 2004 Dec 9;6(25):4727-30.

Cyclic sulfamidates as vehicles for the synthesis of substituted lactams.

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  • 1School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK.


[reaction: see text] A structurally diverse series of mono- and disubstituted 1,2- and 1,3-cyclic sulfamidates react with stabilized enolates, including malonate and phosphonoacetate variants, to provide, after lactamization, substituted and alpha-functionalized pyrrolidinone and piperidinone derivatives.

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