Solvent-equilibrated homoadamantyl chloride ion pairs from chloroformate or oxachlorocarbene fragmentations

Org Lett. 2004 Nov 11;6(23):4293-6. doi: 10.1021/ol040055w.

Authors

Robert A Moss¹, Jingzhi Tian, Ronald R Sauers

Affiliation

¹ Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903, USA. moss@rutchem.rutgers.edu

PMID: 15524466
DOI: 10.1021/ol040055w

Abstract

Fragmentations of 3-homoadamantyl chloroformate and 3-homoadamantyloxychlorocarbene produce identical ion pairs as product-determining intermediates.