Surface-charge-governed ion transport in nanofluidic channels

Phys Rev Lett. 2004 Jul 16;93(3):035901. doi: 10.1103/PhysRevLett.93.035901. Epub 2004 Jul 15.

Abstract

A study of ion transport in aqueous-filled silica channels as thin as 70 nm reveals a remarkable degree of conduction at low salt concentrations that departs strongly from bulk behavior: In the dilute limit, the electrical conductances of channels saturate at a value that is independent of both the salt concentration and the channel height. Our data are well described by an electrokinetic model parametrized only by the surface-charge density. Using chemical surface modifications, we further demonstrate that at low salt concentrations, ion transport in nanochannels is governed by the surface charge.