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Chem Commun (Camb). 2004 Mar 21;(6):694-5. Epub 2004 Feb 13.

Phosphabarrelene-rhodium complexes as highly active catalysts for isomerization free hydroformylation of internal alkenes.

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  • 1Institut für Organische Chemie und Biochemie, Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104 Freiburg, Germany. bernhard.breit@organik.chemie.uni-freiburg.de

Abstract

A new class of phosphabarrelene-rhodium catalysts is described which allows for the first time hydroformylation of internal alkenes with very high activity and which proceeds essentially free of alkene isomerization.

PMID:
15010785
[PubMed]
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