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Chem Commun (Camb). 2004 Jan 7;(1):26-7. Epub 2003 Nov 21.

Synthesis of carbon nitride nanotubes with the C(3)N(4) stoichiometry via a benzene-thermal process at low temperatures.

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  • 1Department of Chemistry, University of Science and Technology of China, Hefe, Anhui 230026, PR China.


In this communication, we first report the direct synthesis of high-quality carbon nitride nanotubes (CNNTs) with inner diameters of 50-100 nm and wall thicknesses of 20-50 nm with the C(3)N(4) stoichiometry on a high-yield of 40%via a simple benzene-thermal process involving the reaction of C(3)N(3)Cl(3) with NaN(3) in a Teflon-lined autoclave at 220 [degree]C without using any catalyst or template.

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